Reactions of Nitrogen Oxides with Isocyanide

Kinetic Study of Reactions between Nitrile Oxides with Simple Cycloalkynes with DFT Method

In this study, reactions of the simple cycloalkynes with substituted Nitrile Oxides, by DFT method will be discussed. The investigation of the structural properties, theoretical thermodynamic and kinetic data, i.e., the activation free energies(DG*), the free energies changes of reaction(DrG) and rate constants of the reactions (k) in 298 K and effects of Electron-withdrawing and...

Control of Nitrogen Oxides

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride.

Gaseous HCl generated from a variety of sources is ubiquitous in both outdoor and indoor air. Oxides of nitrogen (NO(y)) are also globally distributed, because NO formed in combustion processes is oxidized to NO(2), HNO(3), N(2)O(5) and a variety of other nitrogen oxides during transport. Deposition of HCl and NO(y) onto surfaces is commonly regarded as providing permanent removal mechanisms. H...

Indoor Nitrogen Oxides

Nitrogen monoxide (NO) and nitrogen dioxide (NO2) are gases produced by hightemperature combustion through reactions between nitrogen and oxygen. Both nitrogen in fuel and nitrogen in the air can participate in the reactions. Formation of NO can be followed by further oxidation into NO2 in the atmosphere. NO2 is the most toxic of the nitrogen oxides (grouped generically as NOx) and it is very i...

Nitrogen Quadrupole Coupling in the Microwave Ground State Spectra of Tertiary Butyl Isocyanide and Phenyl Isocyanide

Z. Naturforsch. 41 a, 1302-1306 (1986); received August 7, 1986 The microwave ground state spectra of tert.-butyl isocyanide, (CH3)3CNC, and phenyl isocyanide, C6H 5NC, have been measured by microwave Fourier transform spectroscopy in the region 5.0 to 8.0 GHz and analysed for nuclear quadrupole hyperfine splitting due to ‘*N. The nuclear quadrupole coupling constants are shown to be in accorda...